|AJ Styles||February 14, 2004||Boston, MA||-a-|
|Doug Williams||July 17, 2004||Elizabeth, NJ||-b-|
|John Walters||August 28, 2004||Braintree, MA|
|Jay Lethal||March 5, 2005||Philadelphia, PA|
|Samoa Joe||May 7, 2005||New York, NY|
|Nigel McGuinness||August 27, 2005||Williamsville, NY|
|Brian Danielson||August 12, 2006||Liverpool, England||-c-|
-a- - Defeats CM Punk in a tournament final to become the first champion; title vacated in April of 2004 when Styles commits to wrestle full-time with TNA.
-b- - Defeats Alex Shelley in a tournament final to fill the vacancy.
-c- - Unifies the Pure Title with the ROH Heavyweight Title.